Studies on the Structure and Catalytic Properties for Heck Reaction of Troxerutin Supported Palladium Catalyst

Theoretical Foundations of Chemical Engineering - Troxerutin supported palladium (TXT-Pd) catalyst was prepared readily by using one-step synthetic method. As-fabricated TXT-Pd catalyst was...     

脉冲高度权重技术测量197Au中子俘获截面

脉冲高度权重技术是利用C_6D_6探测器测量中子俘获截面的一种数据处理方法。在中国散裂中子源(China Spallation Neutron Source,CSNS)的反角白光中子源(Back-n)靶站上,通过测量金靶(~(197)Au)的中子俘获截面,验证了该方法的可靠性。首先利用Geant4蒙特卡罗程序模拟给出了不同靶条件下的探测器效率,脉冲高度权重函数等基本项,使得加权后的探测器效率与γ能量成正比。然后通过实验测量了~(197)Au中子俘获截面。结果表明:测量获得的中子俘获截面数据和ENDF/B-VⅢ.0评价数据相符合,同时发现随着实验靶尺寸的不同和质子束功率的增加,会使得实验本底的扣除误差越来越大。     

(Metal yolk)/(porous ceria shell) nanostructures for high-performance plasmonic photocatalysis under visible light

We describe a route to the preparation of (metal yolk)/(porous ceria shell) nanostructures through the heterogeneous growth of ceria on porous metal nanoparticles followed by the calcination-induced shrinkage of the nanoparticles. The approach allows for the control of the ceria shell thickness, the metal yolk composition and size, which is difficult to realize through common templating approaches. The yolk/shell nanostructures with monometallic Pt and bimetallic PtAg yolks featuring plasmon-induced broadband light absorption in the visible region are rationally designed and constructed. The superior photocatalytic activities of the obtained nanostructures are demonstrated by the selective oxidation of benzyl alcohol under visible light. The excellent activities are ascribed to the synergistic effects of the metal yolk and the ceria shell on the light absorption, electron-hole separation and efficient mass transfer. Our synthesis of the (metal yolk)/(porous ceria shell) nanostructures points out a way to the creation of sophisticated heteronanostructures for high-performance photocatalysis.

     

Effect of Si on the Microstructure and Oxidation Resistance of Ti-Mo Alloys

JOM - Ti-Mo alloys with various Si alloying additions were prepared by reaction synthesis with Ti powders, Mo powders and Si powders as raw materials. The effect of Si alloying on the...     

山东栖霞—大柳行地区金矿找矿靶区地质评价及优选

栖霞—大柳行地区位于胶东中部栖霞—蓬莱金矿成矿带内，是胶东重要的金成矿区，成矿条件优越。为了对圈定靶区进行优选分类，通过对该区地质背景、找矿靶区评价、找矿靶区优选方面展开综合研究，并结合勘查工作程度和矿业权设置情况，划分出3类预测区，选定了5个靶区为今后优先部署勘查工作的方向。     

广西箭猪坡矿床首次发现的石英脉型锡矿体特征及 锡石微量元素地球化学意义

箭猪坡矿床是丹池成矿带南端的一个以铅锌锑为主的矿床，随着2012-2014年在箭猪坡矿床钻孔中石英脉型锡矿体的首次发现，打开了箭猪坡矿床新的找矿空间。新发现的锡矿体矿石矿物组合类型主要为锡石+闪锌矿+脆硫锑铅矿+黄铁矿+石英及锡石+脆硫锑铅矿+石英+方解石。箭猪坡矿床锡石呈自形-半自形粒状，锡石粒径多在0.1～0.2mm，少数0.02～0.05mm，分布在含硫化物的石英脉裂隙中。物相分析显示箭猪坡矿床锡主要赋存在锡石中，锡石物相占83.33%～100%。阴极发光（CL）图像显示箭猪坡矿床中的锡石经历了两期结晶作用：早期锡石（Ⅰ）和晚期锡石(Ⅱ），早期锡石CL荧光亮度较小，呈暗灰色至黑色；晚期CL荧光亮度较大，呈白色至浅灰色。锡石单矿物SnO2含量91.623%～96.288%，平均94.03%，杂质主要有Fe、W、In等，其中FeO含量0.02%～0.52%，WO3含量多在0.02～1.34%，In2O3含量在0.476%～0.954%，Sn与FeO、In2O3呈负相关，锡石中FeO、WO3、Ta2O5、Nb2O5、MnO含量指示箭猪坡锡形成于中低-中温热液环境，成矿热液来源于高度分异演化的花岗质岩浆。通过与大厂矿田西矿带上部脉状锡矿体的类比分析，具有相似的成矿条件及矿物组合，推测所揭露到的脉状锡矿（化）体相当于西矿带上部脉状锡矿（化）体，而下部的网脉状、似层状锡矿体尚未揭露到，由此预测箭猪坡矿床深部找矿空间及找矿潜力大。     

The Modification of Chrome Tanned Leather by Polyethylene Glycol-Linked Gemini Fatty Alcohol Phosphate

A series of polyethylene glycol-linked Gemini fatty alcohol phosphate surfactants (GFAP) were prepared with long chain n-alkanol (C = 8, 12, 16, 18), polyethylene glycol (PEG-200, PEG-400, PEG-600, PEG-800, PEG-1000) and phosphorus oxychloride (POCl₃). The structure of the prepared surfactants was characterized by Fourier transform infrared spectrometer (FT-IR). The surfactants were employed for the modification of chrome-tanned leather. The morphological changes of chrome-tanned leather and modified chrome-tanned leather were observed by scanning electron microscopy (SEM). The relationship between the alkyl chain length and molecular weight of the PEG and the hydrophobicity, softness, mechanical strength of modified chrome-tanned leather was also discussed. The experimental results showed that the mechanical strength and softness of modified chrome-tanned leather were enhanced with an increase of alkyl chain length, while the hydrophobicity, mechanical strength and softness were decreased with an increase of molecular weight of the PEG. The hydrophobicity, mechanical strength and softness of modified chrome-tanned leather were optimized for an alkyl chain length of 16. Therefore, 16–200 Gemini phosphate surfactants with an alkyl chain length of 16 and a PEG molecular weight of 200 have a good comprehensive modification effect on Chrome-tanned leather, the tensile strength, tear strength and softness of modified chrome-tanned leather are 57.07 N mm⁻², 79.49 N mm⁻¹, 9.73 mm, respectively.     

Effect of Temperature and Strain Rate on the Hot Deformation Behaviour of Ferritic Stainless Steel

Metals and Materials International - The flow behaviour and microstructure characteristics of a ferritic stainless steel were investigated using plain strain compression test on a Gleeble 3500...     

四台矿均压硐室的优化与研究

四台矿属于近距离容易自燃煤层开采,综采工作面采用均压通风系统。在进风顺槽中布置的本巷均压硐室,风机吸风口距离均压风门近,吸风风流经过带式输送机,往往会造成均压风门漏风严重,均压硐室周围温度较高、煤尘较大。据此四台矿优化均压硐室布置方式,采用独立均压硐室代替先前的本巷均压硐室。对优化前后的数据进行研究分析,得出独立均压硐室的应用在减少风门漏风量,降低温度,抑制煤尘方面均有很大改善,实践证明了采用独立均压硐室的可行性及优点。